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Pressure-volume-temperature behaviour of molten polymers

✍ Scribed by B. Rudolf; H. A. Schneider; H. -J. Cantow

Publisher
Springer
Year
1995
Tongue
English
Weight
381 KB
Volume
34
Category
Article
ISSN
0170-0839

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## Abstract The pressure–volume–temperature (__PVT__) dependencies of several amorphous polymers (PS, PC, PPE, and PPE/PS 1:1 blend) in the glassy and molten state were studied. The Simha–Somcynsky (__S__–S) lattice‐hole equation of state (EOS) was used. Fitting the __PVT__ data in the molten state

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The specific volume of thermoplastic polymers and composites with glass fiber have been measured at high pressure, up to 2000 kg/cm2, in the molten state by a dilatometer. The specific volume and thermal expansion coefficient of the melts increase with increasing temperature a t a constant pressure