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Pressure tuning spectroscopy of the metal-metal quadruple bond

✍ Scribed by J. R. Shapley; H. G. Drickamer


Book ID
105102279
Publisher
Springer
Year
1994
Tongue
English
Weight
571 KB
Volume
5
Category
Article
ISSN
1040-7278

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Electronic density topology of metalβ€”met
✍ Anibal Sierraalta πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 369 KB

The nature of the quadruple metal-metal bond for MMo(O&H)., (M=Mo, Cr), and Mo~X~(PH~)~ (X=CI, Br, I) complexes, was investigated using the Bader theory and relativistic pseudopotentials. The topological results show that the direct metal-metal interaction is dominated by a strong charge depletion a