Raman spectra of C60 single crystals, in the pentagon pinch mode frequency region, have been measured as a function of hydrostatic pressure up to 7.2 GPa at room temperature. The softening of the Ag(2) and Hg(8) modes in the pressure region up to 0.4 GPa indicate the orientational ordering phase tra
โฆ LIBER โฆ
Pressure induced rotational ordering phase transition in solid C60
โ Scribed by Ryuji Komori; Yasuhiko Miyamoto
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 334 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0022-3697
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The high symmetry of the C6,, molecule and the symmetry of the cubic lattice site in solid ChO imply that in addition to the known orientational phase transition at 250 K, there is a sequence of transitions at lower T. These transitions correspond to a successive freezing of orientational degrees of