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Pressure effect on phase transitions in MeHAO4 superprotonic conductors (A = S, Se and Me = NH4, Rb, Cs)

✍ Scribed by Sinitsyn, V. V.

Book ID: 118127122
Publisher: Royal Society of Chemistry
Year: 2010
Tongue: English
Weight: 204 KB
Volume: 20
Category: Article
ISSN: 0959-9428
DOI: 10.1039/c0jm00052c

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An __in situ__ X-ray powder diffraction study has shown the cubic modification of (NH~4~)~2~SiF~6~ (cryptohalite, space group __Fm__¯3__m__) at 0.2–0.3 GPa to transform irreversibly into the trigonal bararite, space group __P__¯3__m__1. The anisotropy of lattice strain in the high-pressure phase of