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Pressure dependence of free radical decay in γ-irradiated main chain liquid crystalline polymers

✍ Scribed by F. Szöcs; M. Klimová

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
143 KB
Volume
33
Category
Article
ISSN
0032-3861

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The influence of pressure on the decay of free radicals in irradiated PMMA has been investigated by ESR over the ranges 80-130 ° and 1-13,000 atm. Dependence on pressure of both the rate constants and activation energies for decay has been determined. The influence of pressure on the mechanism of de

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Free radicals were generated in isotactic polypropylene by gamma-irradiation. The samples were annealed at pressures between 1 and 8000 arm and temperatures between 60 and 110 °. The concentration of free radicals was estimated by the ESR method. The rate constants of free radical decay were determi