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Pressure and Temperature Effects on the Molecular Rotation in Acetonitrile-Water Mixtures

✍ Scribed by Masakatsu Ueno; Satoshi Ueyama; Shigenori Hashimoto; Noriaki Tsuchihashi; Kazuyasu Ibuki

Book ID
111594923
Publisher
Springer US
Year
2004
Tongue
English
Weight
273 KB
Volume
33
Category
Article
ISSN
0095-9782

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Pressure effects on the anisotrophic rotational diffusion of acetonitrile-d3 in confined geometry
✍ Shu Xu; Yoo Joong Kim; J. Jonas πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 411 KB

The NMR relaxation behavior of a polar molecular liquid, acetonitrile-ds, confined to porous silica glasses prepared by a solgel process, was studied at pressures up to 5 kbar at 300 K. Analysis of the relaxation data in terms of the two-state fast exchange model and the classical rotational diffusi