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Preparations of novel cage molecules: 2,3,5,6-tetrachalcogena-1,4-disilabicyclo[2.1.1]hexanes

โœ Scribed by Yoshida, Hitoaki.; Kabe, Yoshio.; Ando, Wataru.


Book ID
126126796
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
408 KB
Volume
10
Category
Article
ISSN
0276-7333

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## Novel Conversion of Perfluoro(2,6-dimethyl-1-azacyclohexene) to 3,3,4,4,5-Pentafluoro-2,6-diphenyl-2,6-bis (trifluoromethyl)-1azabicyclo[3.1.0]hexane. -Treatment of perfluoro-azacyclohexene (I) with 2 equiv. of phenyllithium (V) in a cyclohexane/Et 2 O mixture provides access to azabicyclohex