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Preparations and properties of phenanthrene - formaldehyde resins

✍ Scribed by Herbert, Lesley D. ;Robinson, J. Gordon ;Marr, George


Publisher
Wiley (John Wiley & Sons)
Year
1981
Tongue
English
Weight
458 KB
Volume
13
Category
Article
ISSN
0007-1641

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✦ Synopsis


Abstract

Phenanthrene was treated with formaldehyde in the presence of sulphuric acid and the yields of resin obtained were dependent on the acid concentration and on the molar ration of formaldehyde to phenanthrene. All of the resins were composed of dimers, trimers, tetramers and higher oligomers. The bridges joining the phenanthryl units were mainly methylene when formaldehyde was in molar deficit relative to phenathrene, but dimethylene ether and acetal bridges were present when the formaldehyde was in molar excess.


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