## Abstract Phenanthrene‐formaldehyde resins of different oxygen content were reacted with phenol 110°C in the presence of a strong acid catalyst. Cleavage occurred at the dimethylene ether and acetal bridges joining the aromatic nuclei with the concomitant formation of phenanthrene‐formaldehyde‐ph
Preparations and properties of phenanthrene - formaldehyde resins
✍ Scribed by Herbert, Lesley D. ;Robinson, J. Gordon ;Marr, George
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1981
- Tongue
- English
- Weight
- 458 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0007-1641
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✦ Synopsis
Abstract
Phenanthrene was treated with formaldehyde in the presence of sulphuric acid and the yields of resin obtained were dependent on the acid concentration and on the molar ration of formaldehyde to phenanthrene. All of the resins were composed of dimers, trimers, tetramers and higher oligomers. The bridges joining the phenanthryl units were mainly methylene when formaldehyde was in molar deficit relative to phenathrene, but dimethylene ether and acetal bridges were present when the formaldehyde was in molar excess.
📜 SIMILAR VOLUMES
Corn bran (CB) was liquefied in the presence of phenol at high temperature (200°C) under high pressure (Ͼ1 atm) and the obtained liquefied products were reacted with formaldehyde to get phenolated CB/phenol/formaldehyde resins with excellent yields. The properties of the cocondensed resins were exam