Preparation, vibrational spectra, and conformations of 2-substituted 4H,7H-5,6-Benz-1,3,2-dithiaarsepines
β Scribed by R. R. Shagidullin; I. Kh. Shakirov; P. N. Sobolev; N. A. Chadaeva
- Book ID
- 112449670
- Publisher
- Springer
- Year
- 1988
- Tongue
- English
- Weight
- 229 KB
- Volume
- 37
- Category
- Article
- ISSN
- 1573-9171
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An investigation of the molecular dynamics of substituted 1,3,4,5-tetrahydro-2H-l,Ibenzodiazepin-2-0ne derivatives revealed that these molecules adopt cycloheptadiene-like boat conformations. There is an equilibrium between the quasi-axial and the quasiequatorial conformer in which the quasi-axial c
## Abstract The ^1^H and ^13^C NMR spectra of 26 2,3βdihydroβ[1,5]benzoxazepinβ4(5__H__)βone derivatives and four thiono analogues are interpreted in terms of conformational equilibria. Similar to 1,3,4,5βtetrahydroβ2__H__β1,5βbenzodiazepinβ2βones, these compounds favour boat conformations of the s