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Preparation, structure and properties of new ternary arsenides and phosphides: Ni3Zr2P3, Ni3Zr2As3, Ni3Hf2P3 and Ni3Hf2As3

✍ Scribed by E.H El Ghadraoui; J.Y Pivan; R Guerin; J Padiou; M Sergent


Book ID
116015507
Publisher
Elsevier Science
Year
1985
Weight
640 KB
Volume
105
Category
Article
ISSN
0022-5088

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Diammine nickel(II) halides, Ni(NH 3 ) 2 X 2 (X ‫؍‬ Cl, Br, I), were prepared by decomposition of the corresponding hexaammines at 1203C in dynamical vacuum. Their crystal structures are of the Cd(NH 3 ) 2 Cl 2 type (99 -type::, space group Cmmm, Z ‫؍‬ 2): for Ni(NH 3 ) 2 Cl 2 , a ‫؍‬ 8.019 A s , b