Preparation, properties and applications of some new complex metal hydrides of copper, LinCumHn+m

✍ Scribed by E.C. Ashby; A.B. Goel; J.J. Lin

• Book ID: 104235626
• Publisher: Elsevier Science
• Year: 1977
• Tongue: French
• Weight: 205 KB
• Volume: 18
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)83329-3

✦ Synopsis

The chemistry of organocuprates (LiCuR2) and copper hydride (CuH) has been the subject of considerable current interest because of the many synthetic applications l-3of these interesting reagents. Although most organocuprates have reasonable stability in the range -2O'C to +20°C, the greatest limitation of CuH as a reagent is the poor thermal stability of this compound even at temperatures as low as -80°C.4 The ability of CuH to