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Preparation of various alkyl(F-alkyl)ketones and their reactivity towards nucleophiles

✍ Scribed by Patrice Moreau; Naïma Naji; Auguste Commeyras


Book ID
103180496
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
53 KB
Volume
35
Category
Article
ISSN
0022-1139

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Rate constants for the reactions of tert-butoxy radicals (generated by the thermal decomposition of di-tert-butylperoxyoxalate) with several sulfur containing compounds have been measured a t 310 K in benzene. Hexanethiol ( k = 6.5 x lO'M-'s-') reacts considerably faster than alkyl sulfides and disu