Preparation of transparent BN films with superhydrophobic surface
β Scribed by Guo-Xing Li; Yi Liu; Bo Wang; Xue-Mei Song; Er Li; Hui Yan
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 448 KB
- Volume
- 254
- Category
- Article
- ISSN
- 0169-4332
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β¦ Synopsis
A novel approach was investigated to obtain the superhydrophobicity on surfaces of boron nitride films. In this method boron nitride films were deposited firstly on Si(1 0 0) and quartz substrate using a radio frequency (RF) magnetron sputtering system, and then using CF 4 plasma treatment, the topmost surface area can be modified systematically. The results have shown that the water contact angle on such surfaces can be tuned from 678 to 1598. The films were observed to be uniform. The surfaces of films consist of micro-features, which were confirmed by Atomic Force Micrograph. The chemical bond states of the films were determined by Fourier Transform Infrared (FTIR) Spectroscopy, which indicate the dominance of B-N binding. According to the X-ray Photoelectron Spectroscopy analysis, the surface of film is mainly in BN phase. The microfeature induced surface roughness is responsible for the observed superhydrophobic nature. The water contact angles measured on these surfaces can be modeled by the Cassie's formulation.
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## Abstract The relationship between the contact angles, surface tension, and surface roughness is reviewed. Numerical formulas related to the superhydrophobic rough surfaces of polymers are predicted with two approaches, the Wenzel and CassieβBaxter models. With these models as a guide, an artific