Coloured particles have been prepared by dispersion copolymerization of colourless vinyl monomers and polymerizable anthraquinone dyes. The dyes were synthesized by condensation of methacryloy! chloride and amino-or hydroxy-substituted anthraquinones. This paper describes the formation by dispersion
Preparation of thermosensitive magnetic particles by dispersion polymerization
✍ Scribed by Xiao Bin Ding; Zong Hua Sun; Guo Xiang Wan; Ying Yan Jiang
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 504 KB
- Volume
- 38
- Category
- Article
- ISSN
- 1381-5148
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✦ Synopsis
A new kind of thermosensitive magnetic particles with core / shell structure was prepared by copolymerization of styrene (St) and N-isopropylacrylamide (NIPAM) in the presence of Fe O magnetic fluid in ethanol / water medium. The particles 3 4 shrank above the lower critical solution temperature (LCST) of Fe O / P(St-NIPAM) and swelled below the LCST in water.
3 4
The effect of polymerization parameters such as initiator concentration and NIPAM / St ratio on particles was investigated. Higher initiator concentration formed larger Fe O / P(St-NIPAM) particles, and the particles size decreased as the 3 4 NIPAM / St ratio increased.
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