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Preparation of the tris-type complexes of cobalt (III) with two different kinds of .alpha.-amino acids

✍ Scribed by Shibata, Muraji; Nishikawa, Hiroaki; Nishida, Yuzo


Book ID
126878620
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
500 KB
Volume
7
Category
Article
ISSN
0020-1669

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Stereoselectivity in reactions of metal
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## Abstract The synthesis of mixed‐ligand cobalt(III) complexes with (__S__)‐aspartic‐N‐monoacetic acid ((__S__)‐AMA) and different amino‐acids Na[Co((__S__)‐AMA)(AA)] (AA = gly, (__R__)‐ and (__S__)‐ala, val, phe, ser and leu) leads to a mixture of __cis__‐N‐ and __trans__‐N‐isomers. These isomers