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Preparation of the Octahedral d 6 Amido Complex TpRu(CO)(PPh 3 )(NHPh) (Tp = Hydridotris(pyrazolyl)borate): Solid-State Structural Characterization and Reactivity

โœ Scribed by Jayaprakash, K. N.; Gunnoe, T. Brent; Boyle, Paul D.


Book ID
127046040
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
78 KB
Volume
40
Category
Article
ISSN
0020-1669

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The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.