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Preparation of Th3N4 and its oxidation behaviour

โœ Scribed by M. Uno; M. Katsura; M. Miyake


Book ID
116016448
Publisher
Elsevier Science
Year
1987
Weight
937 KB
Volume
135
Category
Article
ISSN
0022-5088

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Preparation of 3,4-di-t-butylthiophene 1
โœ Takashi Otani; Yoshiaki Sugihara; Akihiko Ishii; Juzo Nakayama ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 84 KB

Treatment of 3,4-di-t-butylthiophene 1-oxide with (CF 3 CO) 2 O or (CF 3 SO 2 ) 2 O, followed by reaction with RSO 2 NH 2 , ROC( O)NH 2 , or RCONH 2 furnished a series of 1-imino derivatives of 3,4-di-t-butylthiophene, which carry an electron-withdrawing substituent on the imino nitrogen atom. Treat