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Preparation of soluble TiCl3catalysts by reduction of TiCl4with Grignard reagents and their use for copolymerization of ethylene with propylene

โœ Scribed by Kenya Makino; Kazuichi Tsuda; Mikio Takaki


Publisher
Springer
Year
1991
Tongue
English
Weight
370 KB
Volume
26
Category
Article
ISSN
0170-0839

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Effects of diethyl aluminum chloride (DE
โœ Kyung-Jun Chu; Ho-Sik Chang; Son-Ki Ihm ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 471 KB

TiClfl2.5MgC12(O.5MgEtz )/THF catalyst (R) was prepared by the reduction of TiCI 4 with EtMgC1. The effect of diethyl aluminum chloride (DEAC) addition on the catalytic activity in ethylene-propylene copolymerization was investigated. It was suggested from FT-i.r. that the catalyst R formed similar