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Preparation of potential intermediates for the synthesis of yohimbine and reserpine

✍ Scribed by Polniaszek, Richard P.; Stevens, Robert V.

Book ID
120405695
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
766 KB
Volume
51
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

An Efficient Synthesis of a Potential (βˆ’
An Efficient Synthesis of a Potential (βˆ’)-Reserpine Intermediate from (βˆ’)-Shikimic Acid of the Chiral Pool
✍ Jian Huang; Fen-Er Chen πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 German βš– 92 KB

## Abstract A highly stereoselective route to the polysubstituted chiral octahydrobenzofuran **12**, a potential synthon for the __E__‐ring core in the (βˆ’)__‐__reserpine synthesis, is described. The __Ξ±__‐bromo acetal **11** was obtained from inexpensive (βˆ’)‐shikimic acid (**3**) through a series o