Preparation of poly(phthalazinone ether sulfone ketone) hollow fiber membrane for gas separation

✍ Scribed by Haitao Fu; Daling Yang; Shouhai Zhang; Xigao Jian

• Publisher: John Wiley and Sons
• Year: 2007
• Tongue: English
• Weight: 308 KB
• Volume: 105
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/app.25884

✦ Synopsis

Abstract

Poly(phthalazinone ether sulfone ketone) (PPESK) asymmetric hollow fiber membranes for gas separation were prepared by dry/wet phase inversion technique. The effects of various preparation conditions such as solvent, nonsolvent‐additives(NSA), PPESK concentration, and air gap on the membrane performance were studied. The heat resistance of the PPESK hollow fiber membrane was also examined. The hollow fiber membrane prepared from solvent with stronger solubility showed low gas permeation and high O~2~/N~2~ selectivity due to the denser skin layer. Hollow fiber membrane made from PPESK/DMAc/EtOH/THF system had thicker skin layer than that made from PPESK/DMAc/GBL system with the same ratio of near‐to‐cloud‐point of NSA, which resulted in the higher O~2~/N~2~ selectivity. Along with the increase of NSA content, the gas permeation increased and the O~2~/N~2~ selectivity decreased. The O~2~/N~2~ selectivity of hollow fiber membranes made from PPESK/DMAc/GBL and PPESK/DMAc/EtOH/THF systems were 4.9 and 4.8 respectively, when the membrane forming systems contained appropriate content of NSA. The high polymer concentration resulted in low gas permeation and high O~2~/N~2~ selectivity. When the air gap was excessively long, the membrane performance dropped because of the damage to the dense skin layer. There was no significant drop on the membrane performance when the operation temperature was elevated to 90°C. The average O~2~/N~2~ selectivity was higher than 3.0 at 70°C during a long period of 55 days' test time. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007