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Preparation of Perhydroisoquinolines via the Intramolecular Diels−Alder Reaction of N -3,5-Hexadienoyl Ethyl Acrylimidates: A Formal Synthesis of (±)-Reserpine

✍ Scribed by Sparks, Steven M.; Gutierrez, Arnold J.; Shea, Kenneth J.


Book ID
121492982
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
241 KB
Volume
68
Category
Article
ISSN
0022-3263

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Diastereoselective intramolecular diels-
✍ Tadao Uyehara; Naoki Chiba; Ichiro Suzuki; Yoshinori Yamamoto 📂 Article 📅 1991 🏛 Elsevier Science 🌐 French ⚖ 264 KB

## Total synthesis of C-t)-sedridine, the piperidine alkaloid, was accomplished on the basis of diastereoselecthe intramolecvlarDieh4lderiels-Alderreactign oftbe J,d-unsahmted N-alkoxycahnyl-l-aza-1,3-butaohe genemtedin situ tivm N&imetiyL6iyI-I-aza-but&ens and the cMomtiite of +mten-24.