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Preparation of Partially Substituted 1-Halo- and 1,4-Dihalo-1,3-dienes via Reagent-Controlled Desilylation of Halogenated 1,3-Dienes

โœ Scribed by Xi, Zhenfeng; Song, Zhiyi; Liu, Guangzhen; Liu, Xiaozhong; Takahashi, Tamotsu


Book ID
120023284
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
116 KB
Volume
71
Category
Article
ISSN
0022-3263

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A simple preparation of several new 2,3-
โœ Alexander J. Bridges; John W. Fischer ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 123 KB

Addition of (pseudo) halogens across the triple bond of 1,4-dichlorobut-2-yne, followed by a 1,4-elimination, provides a very simple preparation of ten novel butadienes. In recent years there has been a great deal of interest in asymmetrically substituted butadienes, both for theoretical reasons an