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Preparation of Organometallic Complexed Sugars: Hetero Diels−Alder Reactivity of Tricarbonyl(formyltrimethylenemethane)- iron

✍ Scribed by Kleindl, Paul J.; Donaldson, William A.

Book ID
126413805
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
206 KB
Volume
62
Category
Article
ISSN
0022-3263

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Preparation and Diels-Alder Reactivity o
Preparation and Diels-Alder Reactivity of Tricarbonyliron Complexes of [2.2.2]Hericene
✍ Ulrich Hänisch; Enrico Tagliaferri; Raymond Roulet; Pierre Vogel 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 German ⚖ 595 KB

## Abstract Treatment of [2.2.2]hericene **10** with Fe~2~(CO)~9~ in hexane gave a mixture of monometallic complex **14**, two isomeric dimetallic complexes **15** and **16**, and a trimetallic complex **19** in which all the three diene moieties of **10**, are coordinated. The rate constants of th