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✦ LIBER ✦
Preparation of novel β,β-diphenyl α-(trifluoromethyl)vinylstannane and its cross-coupling reactions with aryl iodides
✍ Scribed by In Howa Jeong; Young Sam Park; Bum Tae Kim
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- French
- Weight
- 79 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
b,b-Diphenyl-a-(trifluoromethyl)vinylstannane 6 was prepared in good yield via several steps from 2,3,3,3-tetrafluoro-1-phenyl-1-phenylthiopropene. The cross-coupling reactions of 6 with aryl iodides in the presence of a catalytic amount of Pd(PPh 3 ) 4 and CuI provided trifluoromethylated triphenylethene derivatives 7 in high yields.
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