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Preparation of novel β,β-diphenyl α-(trifluoromethyl)vinylstannane and its cross-coupling reactions with aryl iodides

✍ Scribed by In Howa Jeong; Young Sam Park; Bum Tae Kim


Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
79 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis


b,b-Diphenyl-a-(trifluoromethyl)vinylstannane 6 was prepared in good yield via several steps from 2,3,3,3-tetrafluoro-1-phenyl-1-phenylthiopropene. The cross-coupling reactions of 6 with aryl iodides in the presence of a catalytic amount of Pd(PPh 3 ) 4 and CuI provided trifluoromethylated triphenylethene derivatives 7 in high yields.


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ChemInform Abstract: Preparation of Nove
✍ In Howa Jeong; Young Sam Park; Bum Tae Kim 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

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