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Preparation of novel pyridine-based, thermally stable poly(ether imide)s

✍ Scribed by Shahram Mehdipour-Ataei; Hani Heidari

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
67 KB
Volume
91
Category
Article
ISSN
0021-8995

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✦ Synopsis

Abstract

Two aromatic, pyridine‐based ether diamines were prepared by the nucleophilic aromatic substitution reaction of 4‐aminophenol and 5‐amino‐1‐naphthol with 2,6‐dichloropyridine in N‐methyl‐2‐pyrrolidone as a solvent. Polycondensation reactions of the obtained diamines with pyromellitic dianhydride, benzophenone tetracarboxylic dianhydride, and hexafluoroisopropylidene diphthalic anhydride resulted in six pyridine‐based, thermally stable poly(ether imide)s. The prepared monomers and polymers were characterized by common spectroscopic methods. The physical and thermal properties of the polymers, including the thermal behavior, thermal stability, solubility, and solution viscosity, were studied. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 22–26, 2004

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