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Preparation of Nitroform from Isopropanol and Study of the Reaction Mechanism

โœ Scribed by Ding, Peng; Wen, Liang; Wang, Huiying; Cheng, Guangbin; Lu, Chunxu; Yang, Hongwei

Book ID
125807209
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
398 KB
Volume
53
Category
Article
ISSN
0888-5885

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Kinetics and equilibrium of the nitrofor
Kinetics and equilibrium of the nitroform-aldehyde-alcohol reaction
โœ C.S. Rondestvedt Jr.; M. Stiles; A.L. Krieger ๐Ÿ“‚ Article ๐Ÿ“… 1963 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 860 KB

The reaction of nitroform.van aldehyde, and an alcohol yields a trinitroether in a reversiblereaction. The probable mechanism involves rapid formation of the hemiacetal, conversion to an alkoxycarbonium ion, and reaction with nitroformate anion. The product is attacked by excess alcohol and is conv