The preparation of three different types of mixed nickel oxides is described. These systems include: (i) the perovskite LaNiO 3 oxide, (ii) a mixed-oxide derived from a hydrotalcite precursor, and (iii) the spinel-type NiAl 2 O 4 oxide. These systems were prepared with the aim of studying the activa
Preparation of niobates of rhodium and nickel and their catalytic behaviors during calcination and reduction treatments
✍ Scribed by K. Kunimori; H. Shindo; H. Oyanagi; T. Uchijima
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 562 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0920-5861
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✦ Synopsis
Double oxides of Rh and Ni have been prepared by chemical mixing methods. Silica-supported and unsupported RhNbO4 and NiNbE06 catalysts exhibited strong metal-oxide interaction behaviors in ethane hydrogenolysis activities after the decomposition of the double oxides by Hz reduction at 500 'C. Silica-supported and zeolite-supported RhV04 catalysts showed high activity and selectivity for dehydrogenation of cyclohexane after the decomposition in Hz. The double-oxide catalyst systems can be used as starting materials to obtain high-performance metal catalysts (redispersion of metals by Hz reduction and regeneration of catalysts by calcination at a high temperature).
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