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Preparation of Nickel-on-Charcoal (Ni/C):. An Improved Protocol

✍ Scribed by Bruce H. Lipshutz; Stefan Tasler


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
74 KB
Volume
343
Category
Article
ISSN
1615-4150

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Dispersed atomic nickel(0) is formed during the reaction of the nickel-s-organyl complexes with silanol groups at temperatures below 373 K. That nickel is oxidized to Ni(I) by protons of the silanol groups in a consecutive step. The Ni(I) portion amounts to about 70% w/w of the Ni used. Six differen