Preparation of NHC Borane Complexes by Lewis Base Exchange with Amine− and Phosphine−Boranes
✍ Scribed by Brahmi, Malika Makhlouf; Monot, Julien; Desage-El Murr, Marine; Curran, Dennis P.; Fensterbank, Louis; Lacôte, Emmanuel; Malacria, Max
- Book ID
- 121258861
- Publisher
- American Chemical Society
- Year
- 2010
- Tongue
- English
- Weight
- 846 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Vibrational spectra of the two Lewis cxnplexes, phosphine borane, PH3BH3, and trifluorophosphine borane, PF3BH3, have been investigated for several isotopic species preserving C3u symmetry. New assignments are proposed and sutstantiated by normal coordinate analyses formulated in the compliance cons
This reaction was very fast, so it is necessary to moderate the reaction velocity by adding ether to the system. \*\* Pyridine-borane was used.
The ability of trialkyl Group 14 triflates in combination with amine and pyridine bases to dehydrogenate amine-and phosphane-borane adducts has been investigated. By using multinuclear NMR spectroscopy, it has been shown that Me 2 NH•BH 3 ( ) is efficiently converted to [Me 2 N-BH 2 ] 2 ( ) by the s