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Preparation of new functionalized hydrocarbon linkers via Suzuki cross coupling reaction

✍ Scribed by Cécile Vanier; Alain Wagner; Charles Mioskowski

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
236 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

Treatment of a vinyl resin with 9-BBN affords a polymer bound alkylborane that undergoes palladium-catalyzed Suzuki cross coupling reactions with a variety of aromatic, vinylic and aliphatic halides. The mild reaction conditions are compatible with several functional groups and allow carbon-carbon bond formation at non-activated positions.

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