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Preparation of Nanostructured Polyaniline and its Super-Amphiphilic Behavior

โœ Scribed by Haibin Zhang; Jixiao Wang; Zhibin Zhou; Zhi Wang; Fengbao Zhang; Shichang Wang


Book ID
102496415
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
321 KB
Volume
29
Category
Article
ISSN
1022-1336

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โœฆ Synopsis


Abstract

PANI nanofibers are prepared electrochemically by templateโ€free method on a stainless steel electrode. Both the hydrophilicity and the lipophilicity of the modified SS surface are enhanced by the nanostructured PANI, and a superโ€amphiphilic surface is obtained in this way. The influence of polymerization conditions, such as polymerization potentials, polymerization time, the acidity, and the dopants on the superโ€amphiphilic property, has been systematically investigated. In addition, the mechanisms of obtaining a superโ€amphiphilic surface are briefly discussed.

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## Abstract A novel approach has been explored to prepare brainโ€like polyaniline (PANI) nanostructures with many convolutions (140โ€“170 nm in average diameter) using aniline/citric acid (CA) salt as the template and chlorine gas as the oxidant by a gas/solid reaction for the first time. The method p