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Preparation of N-(Dichloromethylene)-chlorosulfonamide and -fluorosulfonamide

✍ Scribed by Dr. H. W. Roesky; Dipl.-Chem. U. Biermann


Publisher
John Wiley and Sons
Year
1967
Tongue
English
Weight
244 KB
Volume
6
Category
Article
ISSN
0044-8249

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New Synthesis of N-(Dichloromethylene)ca
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Carbonyl fluoride, COF2, reacts with alkali fluorides MF (M = K, Rb, or Cs) in acetonitrile at room temperature, giving trifluoromethoxides, MOCF3 [I]. After the analogous reaction of thiocarbonyl fluoride, CSF2, \