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Preparation of N-(Aryl)amino Acids from Nitroaryl Compounds and Alcohols

โœ Scribed by MILLER, ROBERT E.; SHARP, DEXTER B.


Book ID
120215188
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
672 KB
Volume
26
Category
Article
ISSN
0022-3263

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Preparation of polynitro compounds from
โœ H. Feuer; G.B. Bachman; C.R. Koller; W.A. Swarts ๐Ÿ“‚ Article ๐Ÿ“… 1963 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 776 KB

Amino acid esters, formaldehyde and trinitromethane react readily in a Mannich type condensation to form N-trinitroethylamino acid esters in good yields. These products decompose slowly on standing but are stabilized by further nitration to the N-nitro-Ntrinitroethylamino esters. Hydrolysis of the e