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Preparation of mono-15N-cyanogen and mono-13C-cyanogen

✍ Scribed by Rolf Wilmes; Manfred Winnewisser

Publisher
John Wiley and Sons
Year
1992
Tongue
French
Weight
209 KB
Volume
31
Category
Article
ISSN
0022-2135

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✦ Synopsis

Abstract

The preparation of the unsymmetrically isotope‐labelled title compounds was achieved in pure form for the first time. While mono‐^15^N‐cyanogen is available in a two‐step‐synthesis, the preparation of mono‐^13^C‐cyanogen requires five steps, the last step in both cases being the dehydration of mono‐^15^N‐e.g. mono‐^13^C‐oxamide with phosphorus pentoxide.

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