Activation of dithioformate by iron comp
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Dilip V. Khasnis; Nadine Pirio; Daniel Touchard; Loïc Toupet; Pierre H. Dixneuf
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Article
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1992
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Elsevier Science
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English
⚖ 896 KB
BH, containing iron complexes Fe(q'-HB(H),SCHSR')(CO)(PR,), (3) were prepared by reduction of Fe(q'-CS,R')(X)(CO)(PR& derivatives (2) with NaBH,. The X-ray structure of 3a (R' = R = Me) shows the cis addition of the H-and BH, fragments to the coordinated dithioformate C-S bond and that one B-H bond