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Preparation of Methyl 4,6-O-benzylidene-2-deoxy-2-nitro-β-D-glucopyranoside from the corresponding 3-deoxy-3-nitro derivatives with sodium nitrite

✍ Scribed by Tohru Sakakibara; Rokuro Sudoh

Book ID
108308415
Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
428 KB
Volume
50
Category
Article
ISSN
0008-6215

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✍ Akinori Seta; Kiohisa Tokuda; Miki Kaiwa; Tohru Sakakibara 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 755 KB

The conformationally flexible title compounds were prepared and subjected to reduction with sodium borodeuteride. Deuteride ion attacks exclusively from the side opposite of the anomeric methoxyl group. However, the stereoselectivity of a similar reduction of the corresponding 4,6-O-benzylidene-~-I>