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Preparation of meso-1,3-diphenylallyllithium·(−)-sparteine—its crystal structure and reactions

✍ Scribed by Felix Marr; Roland Fröhlich; Dieter Hoppe

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
234 KB
Volume
13
Category
Article
ISSN
0957-4166

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✦ Synopsis

The X-ray crystal structure of 1,3-diphenylallyllithium, complexed with enantiomerically pure (-)-sparteine, was determined. The crystallized complex is stereohomogeneous. Its subsequent electrophilic substitution reactions proceed with low enantioselectivity.

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