Preparation of latex carriers for controlled release by concentrated emulsion polymerization
β Scribed by Kyu-Jun Kim; Eli Ruckenstein
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 548 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
Spherical latexes of submicron diameter containing a model hydrophobic herbicide, namely, 2-(2,4-dichlorophenoxy)-propionic acid, were prepared by the concentrated emulsion polymerization method. A mixture of styrene, herbicide, and initiator was dispersed into a small amount of water (6% by volume based on the entire emulsion) containing surfactant, at room temperature. The heating at 4OoC of the foam like gel thus obtained led to the formation of latexes containing the herbicide. It was found that the model herbicide dispersed in the polymer latex was released to water over a period of several weeks and that the amount released was strongly dependent upon temperature and latex concentration in water.
π SIMILAR VOLUMES
Alkali-soluble random copolymer (ASR), poly(styrene/a-methylstyrene/ acrylic acid) [M n : 4,300; acid number: 190], was used as a polymeric emulsifier in the emulsion polymerization of styrene and methyl methacrylate, respectively. ASR containing a large number of carboxyl groups could form aggregat
Heterogeneous latexes were prepared by a two-stage seeded emulsion polymerization process at 80ΠC using potassium persulfate as the initiator and sodium dodecyl sulfate as the emulsifier. Poly(styrene-co-methacrylic acid) latexes containing varying amounts of methacrylic acid (MAA) were used as seed