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Preparation of ketones by a novel decarbalkoxylation of β-keto esters: stereoelectronic assistance to CC bond fission

✍ Scribed by R. Aneja; W.M. Hollis; A.P. Davies; G. Eaton

Publisher: Elsevier Science
Year: 1983
Tongue: French
Weight: 210 KB
Volume: 24
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)86215-2

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✦ Synopsis

Reaction of @-keto esters with the sodium derivative of propane-1,2-diol in an excess of anhydrous propane-1,2-diol causes facile decarbalkoxylation to ketones in excellent yields.

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