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Preparation of Isocyanates from Carbamates by Reaction with Phosgene

✍ Scribed by Dr. H. Ulrich; B. Tucker; Dr. A. A. R. Saytgh


Publisher
John Wiley and Sons
Year
1967
Tongue
English
Weight
230 KB
Volume
6
Category
Article
ISSN
0044-8249

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✦ Synopsis


gram [SiOz; solvent, benzene/cycIohexane (1 :9)] showed a double spot, which is attributed to presence of the mixture of tautomers (4a)/(4b). (3a) + (I)-Li 1 J3 L (40) Jz (4b)


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The Reaction of Cyanothioformamide with
✍ Roger Ketcham; Ernst Schaumann; Gunadi Adiwidjaja πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 282 KB πŸ‘ 2 views

The reactions of the title compounds are governed by sulfur redox chemistry. Thus, cyanothioformamide 2 reacts with aryl isocyanates 3a-c to give bis[3-aryl-1-(arylcarbamoyl)-2oxo-4-(arylcarbamoylimino)imidazolidin-5-yl] disulfides 6, as shown by an X-ray crystallographic investigation of product 6a