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Preparation of indole-2-carboxamides by palladium-catalysed carbonylation

✍ Scribed by John M. Herbert; Alan H. McNeill


Book ID
104258970
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
284 KB
Volume
39
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Intramolecular amination catalysed by ru
✍ S. Cenini; E. Bettettini; M. Fedele; S. Tollari πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 402 KB

The carbonylation in toluene of 2nitrochalcones at 20 bar and lOO"C, with Pd(TMB), as catalyst and TMPhen as cocatalyst (TMBH = 2,4,6-trimethyl benzoic acid; TMPhen = 3,4,7,8-tetramethyl-l,lO-phenantbroline) gave the corresponding 2-acyl indoles in 60-98% yields. The use as catalyst of Ru,(CO),, ac