Preparation of indole-2-carboxamides by palladium-catalysed carbonylation
β Scribed by John M. Herbert; Alan H. McNeill
- Book ID
- 104258970
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 284 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The carbonylation in toluene of 2nitrochalcones at 20 bar and lOO"C, with Pd(TMB), as catalyst and TMPhen as cocatalyst (TMBH = 2,4,6-trimethyl benzoic acid; TMPhen = 3,4,7,8-tetramethyl-l,lO-phenantbroline) gave the corresponding 2-acyl indoles in 60-98% yields. The use as catalyst of Ru,(CO),, ac
Aryl iodides or bromides undergo a Pd (0)-CuI catalysed coupling with 3-(trialkylstannyl) benzo [ 1,4]dioxin-2-carboxamides to provide the corresponding 3-aryl derivatives.
Aryl iodides or bromides undergo a Pd (0)-CuI catalysed coupling with 3-(trialkylstannyl) benzol 1,4]dioxin-2-carboxamides to provide the corresponding 3-aryl derivatives.