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Preparation of hindered esters by the alkylation of carboxylate salts with simple alkyl halides

โœ Scribed by Moore, Gordon G.; Foglia, Thomas A.; McGahan, Timothy J.


Book ID
115518281
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
728 KB
Volume
44
Category
Article
ISSN
0022-3263

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Reaction of alkoxyhydroperoxides with me
โœ G. Cardinale; J.C. Grimmelikhuysen; J.A.M. Laan; F.P. van Lier; D. van der Steen ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 557 KB

A synthesis is described of alkyl chlorides by reaction of methoxy hydroperoxides, prepared from 1-alkenes by oronisation in methanol, with ferric chloride: RCH-CH,\_\*RCH(OOH)OCH,\_\*R= -?RCl. Yields of 1-chlorotetradecane were about 60%; those of other halides from 38 to 57%. INTRGDUCTION When alk