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Preparation of Highly Substituted 4-Aminopyridones via the Reaction of 2-Methylene Dihydrobenzimidazole with Vinyl Isocyanates.

โœ Scribed by James H. Rigby; Chee-Seng Lee


Book ID
101948958
Publisher
John Wiley and Sons
Year
2003
Weight
105 KB
Volume
34
Category
Article
ISSN
0931-7597

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โœ A Arcadi; E Bernocchi; S Cacchi; F Marinelli ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 897 KB

The palladium-catalysed reaction of vinyl triflates with Z-2-buten-1,4-diol affords B-vinyl-u-butyrolactols (4-vinyl-2-hydroxy-tetrahydrofurans) which are converted into the corresponding 8-vinyl-u-butyrolactones by a smooth oxidation with Ag2C03 on celite. Preparation of 8-substituted-v-butyrolacto