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Preparation of Highly Optically Active Substituted 2,3-Methanocinnamyl Alcohols.

โœ Scribed by Nobuyuki Imai; Tetsuro Nomura; Shinya Yamamoto; Yoshihiro Ninomiya; Junzo Nokami


Publisher
John Wiley and Sons
Year
2003
Weight
149 KB
Volume
34
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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ChemInform Abstract: Highly Regioselecti
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Highly Regioselective Opening of Optically Active N-Boc-2,3aziridino Alcohol Derivatives with Metal Halides. -Treatment of silyl-protected N-Boc-aziridino alcohols (chiral and racemic) with MgBr 2 as activated metal halide results in regio-and stereoselective ring opening to give brominated derivat