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Preparation of formaldehyde by photochemical condensation of carbon monoxide and tritiated hydrogen, and the synthesis of a tritiated morphine derivative

✍ Scribed by A. C. Lane; A. McCoubrey; R. Peaker


Publisher
John Wiley and Sons
Year
1966
Tongue
French
Weight
254 KB
Volume
2
Category
Article
ISSN
0022-2135

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✦ Synopsis


Tritiated formaldehyde, required jor labelling 6:ICendo-etheno-7-(2-hydroxy-2-butyl)-tetrahydro-oripavine (M99), was prepared by photochemical condensation of carbon monoxide and tritiated hydrogen. The specijic activity of the M99 (48 C/mmole) was about one half that of the source of isotope. The loss was traced to undefined secondary decompositions during the photochemical reaction.