Preparation of Fluorinated Copolymers by Copper-Mediated Living Radical Polymerization
✍ Scribed by Perrier, Sébastien; Jackson, Stuart G.; Haddleton, David M.; Améduri, Bruno; Boutevin, Bernard
- Book ID
- 123608708
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 160 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0024-9297
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## Abstract Low‐molecular weight amphiphilic diblock copolymers, polystyrene‐__block__‐poly (2‐vinylpyridine) (PS‐__b__‐P2VP), and (P2VP‐__b__‐PS) with different block ratios were synthesized for the first time via organotellurium‐mediated living radical polymerization (TERP). For both the homo‐ an
## Abstract Well defined graft copolymers have been synthesized by a nitroxide‐mediated “living” free radical process using pre‐formed macromonomers. Analysis of the graft systems revealed that the macromonomer was efficiently incorporated into the polymeric backbone to give block copolymers of con