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Preparation of Ethynylcarbinols from the Bisulphite Compounds of Aldehydes and Ketones

โœ Scribed by CYMERMAN, J.; WILKS, K. J.


Book ID
109562192
Publisher
Nature Publishing Group
Year
1950
Tongue
English
Weight
113 KB
Volume
165
Category
Article
ISSN
0028-0836

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Full exploitation of I70-NMR spectroscopy ['] in mechanistic organic chemistry requires efficient, simple methods for the synthesis of I70-labeled compounds. The classical method for labeling aldehydes and ketones with 1 7 0 or I8O is based on their reversible hydration['l. However, to obtain by thi