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Preparation of Esters by Reaction of Ammonium Salts with Alcohols1b

โœ Scribed by Filachione, E. M.; Costello, E. J.; Fisher, C. H.


Book ID
111644708
Publisher
American Chemical Society
Year
1951
Tongue
English
Weight
399 KB
Volume
73
Category
Article
ISSN
0002-7863

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Nitration of ally1 esters with N02BF4 proceeds with nucleophilic participation of carbonyl and yields nitro-substituted oxonium salts. Nitration of alkenes with N02BF4 1 may yield nitroalkenes 'a, 1,2-fluoronitroderivatives lb or solvoadducts I'. Here we report results showing that the interaction