Preparation of donor-acceptor-substituted vinylcyclobutanes
โ Scribed by Gruseck, Ursula ;Heuschmann, Manfred
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1990
- Tongue
- English
- Weight
- 489 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0009-2940
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Oligo(para-phenylene)s (DAOPPs) 2a -2d (n ยผ 1 -4) with terminal donor -acceptor substitution (D ยผ C 6 H 13 O, A ยผ NO 2 ) were prepared by applying Suzuki cross-couplings for chain extension and end capping. The push -pull effect induces short-reaching polarizations of the chain consisting of conjuga