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Preparation of desmosterol from (20S,22R,S)-3.beta.-acetoxychola-5,23-dien-22-ol

โœ Scribed by Kircher, Henry W.; Rosenstein, Fumiko U.


Book ID
126154321
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
485 KB
Volume
52
Category
Article
ISSN
0022-3263

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## Abstnzck: A new synthesis of the important aldehyde I torn easily available l&Dehydropregnenolone acetate (I6-DPA) in high yield is described. The aidehyde I ip converted to trio1 24, involving a stereaselective generation of all the four chiral centers in the brassinolide side chain. The importa